OXIDATION OF ALPHA,BETA-ENONES AND ALKENES WITH OXONE AND SODIUM-HALIDES - A CONVENIENT LABORATORY PREPARATION OF CHLORINE AND BROMINE

Authors
DIETER RK NICE LE VELU SE
Citation
Rk. Dieter et al., OXIDATION OF ALPHA,BETA-ENONES AND ALKENES WITH OXONE AND SODIUM-HALIDES - A CONVENIENT LABORATORY PREPARATION OF CHLORINE AND BROMINE, Tetrahedron letters, 37(14), 1996, pp. 2377-2380
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
14
Year of publication
1996
Pages
2377 - 2380
Database
ISI
SICI code
0040-4039(1996)37:14<2377:OOAAAW>2.0.ZU;2-#
Abstract
Mixtures of oxone and sodium chloride or sodium bromide afford solutio ns of chlorine or bromine, respectively. These solutions effectively a dd chlorine and bromine to alpha,beta-enones and alkenes. The method a ffords improved yields of 3-alkyl-2-halo-2-cycloalkenones which are so metimes difficult to prepare. Copyright (C) 1996 Elsevier Science Ltd