THE DIELS-ALDER ADDITIONS OF PHENYLCYCLOPENTADIENES - TESTS FOR THE PMO THEORY AND THE DIRADICALOID MODEL

Authors
BERNARDHENRIET C CHANON M
Citation
C. Bernardhenriet et M. Chanon, THE DIELS-ALDER ADDITIONS OF PHENYLCYCLOPENTADIENES - TESTS FOR THE PMO THEORY AND THE DIRADICALOID MODEL, Tetrahedron letters, 37(14), 1996, pp. 2417-2420
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
14
Year of publication
1996
Pages
2417 - 2420
Database
ISI
SICI code
0040-4039(1996)37:14<2417:TDAOP->2.0.ZU;2-C
Abstract
The cycloaddition of phenylcyclopentadiene 1 generated in situ through dehydration of 3-phenylcyclopenten-3-ol 2 with a-thioacrylonitriles 3 (captodative dienophiles) exhibit high regio and stereoselectivity. T he reactions provide access to 2-phenylnorbornene derivatives. Copyrig ht (C) 1996 Published by Elsevier Science Ltd