A STRUCTURALLY CHARACTERIZED AZIDE-BRIDGED DINUCLEAR NICKEL(II) CRYPTATE

Authors
FABBRIZZI L PALLAVICINI P PARODI L PEROTTI A SARDONE N TAGLIETTI A
Citation
L. Fabbrizzi et al., A STRUCTURALLY CHARACTERIZED AZIDE-BRIDGED DINUCLEAR NICKEL(II) CRYPTATE, Inorganica Chimica Acta, 244(1), 1996, pp. 7-9
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
244
Issue
1
Year of publication
1996
Pages
7 - 9
Database
ISI
SICI code
0020-1693(1996)244:1<7:ASCADN>2.0.ZU;2-V
Abstract
The macrobicyclic ligand L2 forms dimetallic Ni-II cryptate species in a delimited pH range, which are further able to include one N-3-anion . The molecular structure of the azide-bridged complex shows an almost linear (NiNNNNiII)-N-II arrangement and a different coordination at t he two metal sites (one Ni-II being octahedral, the other trigonal bip yramidal).