STUDY OF COMPLEXATION OF MONO N-ALKYLCYCLEN AND MONO N-ALKYLCYCLAM WITH HEXACARBONYL METAL M(CO)(6) (M=CR,MO) - SPECIFIC N-1,N-7-DISSYMMETRIC DIALKYLATION OF CYCLEN

Authors
PATINEC V GARDINIER I YAOUANC JJ CLEMENT JC HANDEL H DESABBAYES H
Citation
V. Patinec et al., STUDY OF COMPLEXATION OF MONO N-ALKYLCYCLEN AND MONO N-ALKYLCYCLAM WITH HEXACARBONYL METAL M(CO)(6) (M=CR,MO) - SPECIFIC N-1,N-7-DISSYMMETRIC DIALKYLATION OF CYCLEN, Inorganica Chimica Acta, 244(1), 1996, pp. 105-108
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
244
Issue
1
Year of publication
1996
Pages
105 - 108
Database
ISI
SICI code
0020-1693(1996)244:1<105:SOCOMN>2.0.ZU;2-C
Abstract
Complexation of mono N-alkylcyclen (1) and mono N-alkylcyclam (2) with M(CO)(6) (M=Cr, Mo) yields only one LM(CO)(3) complex, in which the t ertiary amine is not coordinated to the metal. An attempted explanatio n for the N',N-7-dialkylation of cyclen, based on an equilibrium betwe en two fac-LM(CO)(3) (L=mono N-alkylcyclen) complexes which are differ ent in the nature of the coordinated nitrogen, is reported. Specific d issymmetric dialkylation of cyclen is also described by a 'one-pot' me thod and by a 'multi-step' method.