D. Burgler et al., LOCAL-STRUCTURE AND DYNAMICS OF A SEGREGATED C(2X2) SULFUR LAYER ON PD(001) STUDIED BY SCANNING TUNNELING MICROSCOPY, Physical review. B, Condensed matter, 47(15), 1993, pp. 9963-9966
We report a scanning-tunneling-microscopy study of a S overlayer on Pd
(001) obtained by diffusion of S atoms from the bulk to the surface. A
tomically resolved images display the c (2 X 2) symmetry of the satura
tion coverage. A large variety of defects such as steps, vacancies, an
d antiphase domain boundaries were imaged. The high density of domain
boundaries reduces the effective coverage to only 0.4 monolayer and st
abilizes this nonideal overlayer. A model of the growth mechanism is p
roposed. Changes of the atomic structure on a time scale of a few minu
tes were observed and are discussed.