The mechanical functions of the fibre/matrix interlayer as well as its
quantitative parameter dependencies and their influence on the proper
ties of the composite system are discussed, with the theoretical model
being considered under realistic conditions. Corresponding to that a
number of interface structure phenomena of some advanced composite mat
erials, revealed by high voltage and high resolution electron microsco
py, are discussed with respect to their relevance to tile control of c
omposite properties, including complex interlayer systems, which are p
roduced by fibre coating as well as by chemical solid state transport
and exchange reactions. The effects of hooking-together, binding, inte
rnal microcracking, and sublayer formation are demonstrated, and in so
me cases correlated with the mechanical behaviour of the materials as
revealed by in situ tensile tests.