Sm. Hong et al., HISTORY OF ANCIENT COPPER SMELTING POLLUTION DURING ROMAN AND MEDIEVAL TIMES RECORDED IN GREENLAND ICE, Science, 272(5259), 1996, pp. 246-249
Determination of copper concentrations in Greenland ice dated from sev
en millennia ago to the present showed values exceeding natural levels
, beginning about 2500 years ago. This early large-scale pollution of
the atmosphere of the Northern Hemisphere is attributed to emissions f
rom the crude, highly polluting smelting technologies used for copper
production during Roman and medieval times, especially in Europe and C
hina. This study opens the way to a quantitative assessment of the his
tory of early metal production, which was instrumental in the developm
ent of human cultures during ancient eras.