ELECTRICAL-CONDUCTIVITY OF MOLTEN LNCL(3) AND M(3)LNCL(6) COMPOUNDS (LN=LA,CE,PR,ND M=K,RB,CS)

Authors
GAUNE P GAUNEESCARD M RYCERZ L BOGACZ A
Citation
P. Gaune et al., ELECTRICAL-CONDUCTIVITY OF MOLTEN LNCL(3) AND M(3)LNCL(6) COMPOUNDS (LN=LA,CE,PR,ND M=K,RB,CS), Journal of alloys and compounds, 235(2), 1996, pp. 143-149
Citations number
30
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
235
Issue
2
Year of publication
1996
Pages
143 - 149
Database
ISI
SICI code
0925-8388(1996)235:2<143:EOMLAM>2.0.ZU;2-5
Abstract
The electrical conductivities of molten lanthanide chlorides LnCl(3) a nd definite compounds M(3)LnCl(6) (where Ln = La, Ce, Pr, Nd and M = K , Rb, Cs) have been determined. The conductivities were well represent ed as quadratic functions of temperature. The molar conductivities for pure lanthanide chlorides were derived and represented well by an Arr henius-type function of temperature. Electrical conduction in investig ated melts was discussed on the basis of complex formation and polymer ization.