R. Markovic et E. Holzschuh, SYNTHESIS OF NOVEL N-ALKTRIENYLTRICHLOROSILANE VERSATILE REAGENT AND PRECURSOR FOR ORGANIC MONOLAYER FORMATION, Collection of Czechoslovak Chemical Communications, 61(3), 1996, pp. 423-426
Preparation of (Z,Z,Z)-9,12,15-octadecatrienyltrichlorosilane (2) by t
he reaction of the corresponding Grignard reagent with SiCl4 is descri
bed. The novel compound of the type RSiX(3), useful for various organo
metallic applications and with the ability to form close-packed ordere
d monolayers chemically bonded to the surface, was thoroughly characte
rized by spectral analysis.