NMR INVESTIGATION OF HIGH-TEMPERATURE NONLINEAR-OPTICAL POLYMERS

Authors
HENRY RA MERWIN LH NISSAN RA STENGERSMITH JD
Citation
Ra. Henry et al., NMR INVESTIGATION OF HIGH-TEMPERATURE NONLINEAR-OPTICAL POLYMERS, Magnetic resonance in chemistry, 34(4), 1996, pp. 293-300
Citations number
15
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
34
Issue
4
Year of publication
1996
Pages
293 - 300
Database
ISI
SICI code
0749-1581(1996)34:4<293:NIOHNP>2.0.ZU;2-X
Abstract
Two forms of a novel accordion-shaped non-linear optical polymer (NLOP ) based on cis- and trans-1,2-diaminocyclohexane and o-xylyl linkages were characterized by solution- and solid-state NMR spectroscopy. Mode l compounds and the monomers for both the cis and trans forms of these polymers were also investigated. The cis form is less rigid than the trans form, as demonstrated by the fluxional behavior of the cis model in the solution state.