THE ROLE OF LOCALIZATION IN GLASSES AND SUPERCOOLED LIQUIDS

Localized excitations (tunneling modes, soft harmonic vibrations) are believed to play a dominant role in the thermodynamics and transport p roperties of glasses at low temperature. Using instantaneous normal-mo de (INM) analysis, we explore the role that such localization plays in determining the behavior of such systems in the vicinity of the glass transition. Building on our previous study [Phys. Rev. Lett. 74, 936 (1995)] we present evidence that the glass transition in two simple mo del systems is associated with a transition temperature below which al l unstable INM's become localized. This localization transition is a p ossible mechanism for the change in diffusion mechanism from continuou s flow to localized hopping that is believed to occur in fragile glass formers at a temperature just above T-g. (C) 1996 American Institute of Physics.