Gj. Hutchings et al., AMBIENT-TEMPERATURE CO OXIDATION USING COPPER MANGANESE OXIDE CATALYSTS PREPARED BY COPRECIPITATION - EFFECT OF AGING ON CATALYST PERFORMANCE, Catalysis letters, 42(1-2), 1996, pp. 21-24
Copper manganese oxides are prepared using a coprecipitation procedure
and studied for the oxidation of CO at ambient temperature. In partic
ular, the effect of the ageing time, i.e. the time that the precipitat
e remains in contact with the precipitating medium, is investigated. I
t is shown that this parameter is of crucial importance in controlling
the catalytic performance and that catalysts which are aged for less
than or equal to 30 min or greater than or equal to 300 min give the b
est performance. Preliminary characterisation using powder X-ray diffr
action indicates that a combination between CuO and copper manganese o
xide may be responsible for the enhanced activity observed with these
samples.