We report the results of a study on microcavity structures containing
the conjugated polymer poly(2,5-dialkoxy-p-phenylenevinylene). Strong
spectral narrowing, from a full width at half-maximum (FWHM) of 128 to
16 nm for photoluminescence (PL) and 112 to 35 nm for electroluminesc
ence (EL) is observed. Modification of the cavity path length is used
to produce a shift in the PL peak emission wavelength by 50 nm. in add
ition, we show that the EL emission wavelength has a clear angular dep
endence that can be described using a transfer-matrix reflectivity (TM
R) model. These are characteristic signatures of the modification of s
pontaneous emission properties through coupling to resonant cavity mod
es.