Electron transfer (ET) in organic-inorganic hybrid structures is of in
terest for applications in optoelectronics. The study of these hybrid
structures is difficult because contact formation is often destructive
. We have experimented with the lift-off/float-on technique to create
metal contacts in a gentle manner. We present results of these experim
ents and initial data on silicon/octadecyl trichlorosilane (OTS)/silve
r junctions where the metal contact was prepared by evaporation. The p
resence of the OTS greatly affects the current-voltage characteristics
of such a junction.