Electron-probe methods have been used to study the evolution of the to
pology of near-surface macroscopic growth defects and macroscopic defe
cts introduced by mechanical processing in CdxHg1-xTe (x similar or eq
ual to 0.2) crystals. When the samples were stored for a long time, th
e formation of inclusions saturated with mercury or tellurium was obse
rved in the region of the macroscopic defects. The effective self-diff
usion coefficients of mercury, estimated from the growth rate of the m
ercury inclusions at their formation stage, exceeded those known from
the literature. The possible causes of such a discrepancy are discusse
d; they are connected, in particular, with the fact that the mass-tran
sfer process involves internal elastic stresses that arise when the su
rface is mechanically processed, when diffusional fluxes that differ i
n their mechanisms are applied, etc. (C) 1996 American Institute of Ph
ysics.