T. Kimura et al., FABRICATION OF SI AL2O3/SI SILICON-ON-INSULATOR STRUCTURES GROWN BY ULTRAHIGH-VACUUM CVD METHOD/, JPN J A P 1, 35(2B), 1996, pp. 1001-1004
A double-heteroepitaxial S/gamma-Al2O3/Si structure was fabricated for
the first time by ultrahigh-vacuum chemical vapor deposition (UHV-CVD
). An epitaxial gamma-Al2O3(100) layer was grown on a Si(100) substrat
e with Al(CH3)(3) and N2O gases at substrate temperatures of 850-1000
degrees C. Subsequently, an epitaxial Si(100) layer was also grown on
a gamma-Al2O3(100)/Si(100) substrate by UHV-CVD with Si2H6 gas at subs
trate temperatures of 750-950 degrees C. These epitaxial layers were c
haracterized by reflection high-energy electron diffraction (RHEED), s
canning electron microscopy (SEM), Auger electron spectroscopy (AES),
cross-sectional transmission electron microscopy (TEM), Hall effect me
asurement and ellipsometry. The reflection high-energy electron diffra
ction of the 5000-Angstrom-thick silicon epitaxial layer indicated str
eaked 2x1 patterns. From these results, the UHV-CVD method is proven t
o be an effective method for Al2O3 and silicon growth at low growth te
mperatures, yielding uniform film thickness and good crystalline quali
ty.