CATALYST CONTROL IN A CHIRAL BORANE-MEDIATED ALDOL REACTION - BOTH SYN-ALDOL AND ANTI-ALDOL IN ALMOST OPTICALLY PURE STATE OBTAINED FROM ONE RACEMIC ALDEHYDE

Authors
KIYOOKA S KIRA H HENA MA
Citation
S. Kiyooka et al., CATALYST CONTROL IN A CHIRAL BORANE-MEDIATED ALDOL REACTION - BOTH SYN-ALDOL AND ANTI-ALDOL IN ALMOST OPTICALLY PURE STATE OBTAINED FROM ONE RACEMIC ALDEHYDE, Tetrahedron letters, 37(15), 1996, pp. 2597-2600
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
15
Year of publication
1996
Pages
2597 - 2600
Database
ISI
SICI code
0040-4039(1996)37:15<2597:CCIACB>2.0.ZU;2-F
Abstract
Chiral borane (L-2 and D-2)-mediated aldol reaction proceeded with chi ral aldehydes (1, 5, and 9) in a manner of ''catalyst control''. Both enantiomers were obtained from one racemic aldehyde in almost opticall y pure state. Copyright (C) 1996 Elsevier Science Ltd