5,10-Dimethyl[13]annulenone, the first monocyclic annulenone larger th
an tropone, was synthesized by catalytic partial hydrogenation of 5,10
-dimethylbisdehydro[13]annulenone. The H-1 NMR data indicate that the
compound is completely atropic. Molecular mechanics studies suggest th
e nonplanarity of the ring and thus the lack of peripheral conjugation
. Copyright (C) 1996 Elsevier Science Ltd