Effects of Ar-ion implantation on the surface structure of a pyrolytic
graphite (PG) have been investigated by means of the laser Raman spec
troscopy and X-ray photoelectron spectroscopy (XPS). The implantation
was conducted to both the basal and edge surfaces, whereby the carbon
lattice was destroyed so as to form an amorphous structure at the flue
nce level of 2.3 x 10(16) ions cm(-2). A new asymmetric Raman band was
produced around 1200-1300cm(-1) for the edge surface at 1.0 x 10(17)
ions cm(-2). The atomic ratio of XPS O/C of the edge surface was not a
ppreciably changed by the bombardment between 1.0 x 10(14) and 1.0 x 1
0(15) ions m(-2). The outermost structure of the edge surface seems to
be less damaged at these fluence levels than that of the basal surfac
e.