Radiative properties are wavelength dependent; they characterize the m
aterial and the spectrum is its fingerprint. The scattering is control
led by the physical aspect of the material and, for example, radiative
properties are affected by the surface state of the sample, the parti
cle size in case of powders, the aspect ratio (length/diameter) and th
e orientation of the fibers in case of fibrous materials. It is import
ant to know the radiative properties of materials in order to evaluate
the radiative heat transfer. Bandwidths and relative intensities vary
with these physical parameters which determine the radiative behavior
of the material. The results presented in this paper all refer to ref
lectances of natural and synthetic fibrous and powdered polymers. The
effect of different parameters such as the composition of the material
and its surface state on reflectances is shown via principal componen
t analysis.