M. Okumiya et al., APPLICATION OF PROBE METHOD TO CARBON CON TENT CONTROL IN PLASMA CARBURIZING LOW-CARBON STEEL, Nippon Kinzoku Gakkaishi, 60(2), 1996, pp. 225-230
In the plasma carburizing process, the influence of electron temperatu
re and electron density measured by a langmuir probe on carbon content
was studied on low carbon steel foils of 0.25 mm in thickness. The in
creases in plasma current and plasma voltage cause the decreases in el
ectron temperature. The carbon content decreases curvilinearly as the
electron temperature increases. Generally the carbon content approxima
tely 0.8 mass% is targeted to obtain an effective mechanical property.
But the decreasing rate of carbon content to electron temperature at
around 0.8 mass%C is large, so a highly accurate control with electron
temperature is difficult. The increase in plasma current and plasma v
oltage cause the increases in electron density. The carbon content inc
reases linearly as electron density increases. Negative charges balanc
e with positive charges in plasma, so the density of positively charge
d carbon ions increases as the electron density increases, hence the c
arbon content increases. Even if the electron temperature or electron
density is constant, the carbon content increases as the premixed meth
ane ratio increases. Because the increase in premixed methane ratio ca
uses the increased retained methane ratio and the increased carbon pot
ential. Even if the plasma current or plasma voltage changes in plasma
carburizing, the carbon content can be predicted and controlled by th
e electron density.