S. Brunner et al., HIGH-RESOLUTION MASS-SPECTROMETRY OF LIGHT-IONS IN A PENNING TRAP, Rapid communications in mass spectrometry, 10(5), 1996, pp. 573-579
After a brief introduction to the electromagnetic ion trap, we concent
rate on the problems related to precise determination of cyclotron fre
quencies of stored ions. Since these frequency measurements are perfor
med in order to obtain mass ratios we want to point out the inherent d
ifficulties in detecting mass ratios different from 1.0. We then descr
ibe the time-of-flight method of detecting ion cyclotron resonance sig
nals. With a small room temperature Penning trap of characteristic siz
e d=1.8 mm in a 7 T magnetic field we study the effect of changing ele
ctrical field anharmonicities (i.e. dodecapole term) and of various to
n numbers on the cyclotron frequency.