HIGH-RESOLUTION MASS-SPECTROMETRY OF LIGHT-IONS IN A PENNING TRAP

Citation
S. Brunner et al., HIGH-RESOLUTION MASS-SPECTROMETRY OF LIGHT-IONS IN A PENNING TRAP, Rapid communications in mass spectrometry, 10(5), 1996, pp. 573-579
Citations number
14
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
ISSN journal
09514198
Volume
10
Issue
5
Year of publication
1996
Pages
573 - 579
Database
ISI
SICI code
0951-4198(1996)10:5<573:HMOLIA>2.0.ZU;2-5
Abstract
After a brief introduction to the electromagnetic ion trap, we concent rate on the problems related to precise determination of cyclotron fre quencies of stored ions. Since these frequency measurements are perfor med in order to obtain mass ratios we want to point out the inherent d ifficulties in detecting mass ratios different from 1.0. We then descr ibe the time-of-flight method of detecting ion cyclotron resonance sig nals. With a small room temperature Penning trap of characteristic siz e d=1.8 mm in a 7 T magnetic field we study the effect of changing ele ctrical field anharmonicities (i.e. dodecapole term) and of various to n numbers on the cyclotron frequency.