Tt. Lin et Mh. Hon, THE GROWTH OF MULTI-STAR CVD BETA-SIC AND SIC TIC COMPOSITES/, Nippon Seramikkusu Kyokai gakujutsu ronbunshi, 104(3), 1996, pp. 174-178
The multi-star beta-SiC and SiC/TiC composites have been deposited by
CVD method on graphite substrate. The precursors, SiCl4, TiCl4 and C3H
8 were used as silicon, titanium and carbon sources, respectively, and
hydrogen as a carrier gas for deposition. The morphology of surface a
nd polished cross section for the SiC and SiC/TiC composite deposited
was observed by SEM. The crystal orientations and microstructrure were
analyzed by XRD and TEM. The growth propagation of the multi-star bet
a-SiC and the SiC/TiC composites is attributed to the twin-plane-reent
rant-edge mechanism. The [220] is an intensely preferred orientation a
s the twin axis of interpenetration twin configuration. The interface
of SiC/TiC is severely strained as found in TEM image and dislocations
are generated in the TIC phases owing to the mismatch of coefficient
of thermal expansion.