The nuclear-resonance photon-scattering technique was used to study th
e tilt angle of physisorbed N2 with respect to the graphene planes Of
C24K prepared from highly oriented pyrolytic graphite. This was done b
y measuring the ratio of the resonantly scattered intensities from the
6324-keV level in N-15 with the photon beam parallel and perpendicula
r to the graphene planes. In the temperature range T = 10-190 K where
nitrogen is molecularly intercalated into the C24K, a huge anisotropy,
a factor almost-equal-to 2.5, was observed in the scattering cross se
ctions. This is interpreted in terms of the orientation of the molecul
ar axes of the N2 molecules as being very nearly parallel to the graph
ene planes. Above 200 K, the amount of molecularly intercalated N2 was
negligible.