STRUCTURE OF TRIBENZYL(THIOCYANATO-N)(TRIPHENYLARSINE OXIDE-O)TIN

Authors
NG SW DAS VGK
Citation
Sw. Ng et Vgk. Das, STRUCTURE OF TRIBENZYL(THIOCYANATO-N)(TRIPHENYLARSINE OXIDE-O)TIN, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 758-760
Citations number
5
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
4
Pages
758 - 760
Database
ISI
SICI code
0108-2701(1993)49:<758:SOTO>2.0.ZU;2-M
Abstract
[Sn(NCS)(C18H15AsO)(C7H7)3], M(r) = 772.42, triclinic, P1BAR, a = 10.0 99 (2), b = 11.4014 (8), c = 15.682 (3) angstrom, alpha = 95.145 (9), beta = 92.72 (2), gamma = 98.29 (1)degrees, V = 1776.3 (5) angstrom3, Z = 2, D(x) = 1.444 g cm-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = 17.30 cm-1, F(000) = 780, T = 300 K, R = 0.030 for 4221 reflections. The Sn atom is five-coordinate in a trans-C3SnNO trigonal bipyramidal environment, being di laced out the equatorial plane by 0.030 (1) angs trom in the direction of the N occupant.