A NEW ONE-DIMENSIONAL COMPOUND - SYNTHESIS AND STRUCTURE OF INNB3(SE2)6

Citation
Sq. Deng et al., A NEW ONE-DIMENSIONAL COMPOUND - SYNTHESIS AND STRUCTURE OF INNB3(SE2)6, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 786-788
Citations number
19
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
4
Pages
786 - 788
Database
ISI
SICI code
0108-2701(1993)49:<786:ANOC-S>2.0.ZU;2-V
Abstract
The new one-dimensional compound, indium niobium selenide, was synthes ized by high-temperature solid-state reactions. The structure is compo sed of [Nb3(Se2)6]infinity chains running along the c axis with In ato ms intercalated between these chains. All the Nb atoms have rectangula r antiprismatic coordination environments. All the Se atoms in the str ucture are in the form of Se2 dimers with Se-Se distances of 2.325 (2) and 2.356 (2) angstrom.