Authors
Citation
Pd. Lickiss et R. Lucas, RATE INCREASES IN THE FLUORINATION OF BULKY CHLOROSILANES CAUSED BY ULTRASOUND OR BY WATER, Journal of organometallic chemistry, 510(1-2), 1996, pp. 167-172
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
0022328X
Volume
510
Issue
1-2
Year of publication
1996
Pages
167 - 172
Database
ISI
SICI code
0022-328X(1996)510:1-2<167:RIITFO>2.0.ZU;2-Z
Abstract
The conversion of bulky chlorosilanes to fluorosilanes under anhydrous
conditions with hexafluorosilicate salts is accelerated by ultrasound
. The fluorination of sterically hindered chlorosilanes such as (1)BuP
h(2)SiCl, in the absence of ultrasound, is greatly accelerated by the
addition of water to the reaction mixture.