For the case of inelastic electron-atom scattering, it has been known
for some time that significant spin effects may be observed even if sp
in-dependent forces on the projectile can be ignored. These spin effec
ts result from the Pauli principle and this phenomenon has become know
n as the fine-structure effect. Recently, the question of whether or n
ot these same types of effects should be observed for atomic ionizatio
n has been considered and the initial indications are that significant
spin asymmetries can also be expected for atomic ionization if the fi
nal ion satisfies LS coupling and the final J state of the ion can be
resolved. In this paper, we consider this problem for electron-impact
ionization of inert gases. The theory of the fine-structure effect is
presented for ionization and first-order distorted-wave results are co
mpared with very recent experimental data.