C. Schaffnit et al., EFFECT OF H-2 CONCENTRATION ON RF PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION OF BORON-NITRIDE COATINGS FROM THE BCL3-N-2-H-2-AR GAS SYSTEM, Surface & coatings technology, 80(1-2), 1996, pp. 13-17
Boron nitride coatings were obtained by r.f. plasma-enhanced chemical
vapour deposition (PECVD) from a BCl3-N-2-H-2-Ar mixture. Preliminary
results on the effect of the hydrogen content in the gas mixture are r
eported. The characterization of the coatings and the gas phase analys
is are discussed. Variations in the hydrogen content in the plasma can
account for the decrease in oxygen content, increase in chlorine cont
ent and change in the B/N ratio in the deposited material. The morphol
ogy of the coatings also depends on the hydrogen content in the gas ph
ase.