NEW RADICAL ALLYLATION REACTIONS USING 2-BROMO-3-(PHENYLTHIO)PROPENE AND THEIR APPLICATION TO THE SYNTHESIS OF CARBOCYCLIC COMPOUNDS

Authors
YOO B CURRAN DP
Citation
B. Yoo et Dp. Curran, NEW RADICAL ALLYLATION REACTIONS USING 2-BROMO-3-(PHENYLTHIO)PROPENE AND THEIR APPLICATION TO THE SYNTHESIS OF CARBOCYCLIC COMPOUNDS, Bulletin of the Korean Chemical Society, 17(11), 1996, pp. 1009-1018
Citations number
52
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Korean Chemical Society → ACNP
ISSN journal
02532964
Volume
17
Issue
11
Year of publication
1996
Pages
1009 - 1018
Database
ISI
SICI code
0253-2964(1996)17:11<1009:NRARU2>2.0.ZU;2-R
Abstract
A study on the application of vinyl radical cyclization via free radic al allylation reaction in the synthesis of various carbocyclic compoun ds is described. In connection with this study, a new allyl transfer r eagent, 2-bromo-3-(phenylthio) propene 1 is developed and it was shown that vinyl radical cyclization through free radical allylation reacti on using reagent 1 provides a valuable approach to carbocyclic systems with a reactive exo-alkylidene moiety, which is advantageous for furt her transformations.