The oxidation behavior of Al-W alloy films (500 Angstrom) deposited on
Cu as a passivation layer to protect Cu from oxidation has been exami
ned by Auger electron spectroscopy and X-ray photoelectron spectroscop
y. The preferential oxidation of Al in the Al-W alloy protects underly
ing W and Cu from oxidation, and simultaneously, Cu is rejected by the
formation of Al2O3 within the system, resulting in a successful separ
ation of Cu from the surface oxidized layer due to the oxidation even
after heating at 500 degrees C for 1 h in air.