(PERYLENE)(3)[BI4BR12] - A NEW ARENE PI-COMPLEX CONTAINING THE [BI4BR12] UNIT

Citation
Lp. Battaglia et al., (PERYLENE)(3)[BI4BR12] - A NEW ARENE PI-COMPLEX CONTAINING THE [BI4BR12] UNIT, Inorganic chemistry, 35(8), 1996, pp. 2390
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
35
Issue
8
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:8<2390:(-ANAP>2.0.ZU;2-I
Abstract
The reaction of perylene with anhydrous bismuth bromide leads to a new structurally characterized pi-arene complex. Arene-bismuth interactio ns and weak pi ...pi perylene-perylene contacts stabilize the molecula r framework of tetrameric Bi4Br12 in the solid state. A one-dimensiona l arene-tetrameric unit-arene packing motif is observed.