A GENUINE EXAMPLE OF A DISCRETE BIMETALLIC (CU, GD) COMPLEX - STRUCTURAL DETERMINATION AND MAGNETIC-PROPERTIES

Authors
COSTES JP DAHAN F DUPUIS A LAURENT JP
Citation
Jp. Costes et al., A GENUINE EXAMPLE OF A DISCRETE BIMETALLIC (CU, GD) COMPLEX - STRUCTURAL DETERMINATION AND MAGNETIC-PROPERTIES, Inorganic chemistry, 35(8), 1996, pp. 2400
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
8
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:8<2400:AGEOAD>2.0.ZU;2-B
Abstract
The LCuGd(NO3)(3) . Me(2)CO complex crystallizes in the monoclinic spa ce group P2(1)/c (No. 14) in a cell having the dimensions a = 9.799(1) Angstrom, b = 18.926(3) Angstrom, c = 16.012(1) Angstrom, beta = 96.5 30(8)degrees, Z = 4. The four units forming the unit cell do not displ ay any obvious short contacts between them. The magnetic behavior is c haracteristic of a ferromagnetic interaction between the Gd3+ and Cu2 ions.