La. Glasgow et Sx. Liu, EFFECTS OF DOSING REGIMEN AND AGITATION PROFILE UPON FLOC CHARACTERISTICS, Chemical engineering communications, 132, 1995, pp. 223-237
The efficiency of solid-liquid separation processes that employ floccu
lation and sedimentation mainly depends upon the characteristics of ag
gregates produced by coagulation. Size and density are foremost, howev
er, most flocculation processes are designed such that many larger flo
cs are formed by floc-floc collisions resulting in the entrapment of l
arge amounts of interstitial water. Thus, as particle size increases,
flee density generally decreases. Not only does this affect the achiev
able rate of sedimentation, but it also contributes to the volume of p
rocess sludge that must be dewatered prior to ultimate disposal. The o
bjective of the present work is to examine combinations of flocculant
dosing and activation along with shear profile or history that can pro
duce flocs of unusually compact structure, thereby increasing the effi
ciency of separation and reducing the volume of sludge produced. Four
types of batch coagulation experiments were conducted, employing both
single and intermittent polymer applications as well as periodic episo
des of elevated shear to provide more compact constituent hoc structur
es. A light obscuration method, in which the increase in diode phototu
be output during sedimentation was used to assess mean aggregate densi
ty, was employed throughout the study; it provided a convenient means
for comparison of the effects of process modifications upon sedimentat
ion.