ESR STUDY OF FORMATION OF ALLYLIC RADICALS IN SIMULTANEOUS PHOTOCHEMICAL GENERATION OF PHOSPHORYL AND CARBON-CENTERED RADICALS IN THE PRESENCE OF C-60 FULLERENE

Citation
Bl. Tumanskii et al., ESR STUDY OF FORMATION OF ALLYLIC RADICALS IN SIMULTANEOUS PHOTOCHEMICAL GENERATION OF PHOSPHORYL AND CARBON-CENTERED RADICALS IN THE PRESENCE OF C-60 FULLERENE, Russian chemical bulletin, 44(12), 1995, pp. 2316-2318
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
44
Issue
12
Year of publication
1995
Pages
2316 - 2318
Database
ISI
SICI code
1066-5285(1995)44:12<2316:ESOFOA>2.0.ZU;2-B
Abstract
Allylic radicals resulting upon simultaneous photochemical generation of phosphoryl [P-.(O)(OPri)(2)] and carbon-centered [C-.(O)OMe, (CH3)- C-., (CCl3)-C-.] radicals in saturated toluene solutions of C-60 have been studied by the ESR method. The donor-acceptor properties of carbo n-centered radicals determine the positions of phosphoryl groups in th e allylic system.