ESR STUDY OF FORMATION OF ALLYLIC RADICALS IN SIMULTANEOUS PHOTOCHEMICAL GENERATION OF PHOSPHORYL AND CARBON-CENTERED RADICALS IN THE PRESENCE OF C-60 FULLERENE

Authors
TUMANSKII BL BASHILOV VV SOLODOVNIKOV SP BUBNOV NN SOKOLOV VI
Citation
Bl. Tumanskii et al., ESR STUDY OF FORMATION OF ALLYLIC RADICALS IN SIMULTANEOUS PHOTOCHEMICAL GENERATION OF PHOSPHORYL AND CARBON-CENTERED RADICALS IN THE PRESENCE OF C-60 FULLERENE, Russian chemical bulletin, 44(12), 1995, pp. 2316-2318
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
12
Year of publication
1995
Pages
2316 - 2318
Database
ISI
SICI code
1066-5285(1995)44:12<2316:ESOFOA>2.0.ZU;2-B
Abstract
Allylic radicals resulting upon simultaneous photochemical generation of phosphoryl [P-.(O)(OPri)(2)] and carbon-centered [C-.(O)OMe, (CH3)- C-., (CCl3)-C-.] radicals in saturated toluene solutions of C-60 have been studied by the ESR method. The donor-acceptor properties of carbo n-centered radicals determine the positions of phosphoryl groups in th e allylic system.