Ap. Litvinchuk et al., SUBSTITUTION OF PR FOR Y IN YBA2CU4O8 AND YBA2CU3.5O7.5-DELTA SUPERCONDUCTORS - PHONON MODES AND CHARGE-TRANSFER EFFECTS, Journal of physics and chemistry of solids, 56(12), 1995, pp. 1833-1833
We report on a Raman scattering study of (YxPr1-x)(2)Ba4Cu6+nO14+n-del
ta (n = 1, 2) superconductors with 0 less than or equal to x less than
or equal to 1 in the temperature range 10-300 K. The observed changes
of the phonon frequencies, including the double chain modes, with Pr-
content x in general follow from the variations of the bond distances.
The apex-oxygen mode is, however, found to exhibit stronger variation
with x in single (n = 0) then in double-chain (n = 1, 2) materials, w
hich may indicate charge redistribution effects between chains and pla
nes.