PREPARATION AND NOVEL COORDINATION STRUCTURE OF [CU(SACCH)(2)(H2O)(2)]CENTER-DOT-4H(2)O

Authors
LI JM ZHOU YH ZHOU GT WANG QM HUANG Q WU XT
Citation
Jm. Li et al., PREPARATION AND NOVEL COORDINATION STRUCTURE OF [CU(SACCH)(2)(H2O)(2)]CENTER-DOT-4H(2)O, Crystal research and technology, 31(2), 1996, pp. 197-202
Citations number
20
Categorie Soggetti
Crystallography
Journal title
Crystal research and technology → ACNP
ISSN journal
02321300
Volume
31
Issue
2
Year of publication
1996
Pages
197 - 202
Database
ISI
SICI code
0232-1300(1996)31:2<197:PANCSO>2.0.ZU;2-O
Abstract
The new complex of copper (II) and saccharin - [Cu(sacch)(2)(H2O)(2)] . 4 H2O (1) has been prepared and determined by single crystal X-ray d iffraction method. It differs from [Cu(sacch)(2)(H2O)(4)] . 2 H2O (2) which was reported by HAIDER et al. (1981). The compound (1) crystalli zes in the monoclinic space group P2(1)/a with lattice parameters a = 7.326(3) Angstrom, b = 16.308(5) Angstrom, c = 8.379(1) Angstrom, beta = 101.09(2)degrees, Z = 2. Copper(II) exists in a square planar struc ture with a C-2 axis and centrosymmetry belonging to the C-2h group.