MANGANESE(III)-CATALYZED OXIDATION OF SULFIDES WITH SODIUM-CHLORITE IN AN APROTIC-SOLVENT IN THE PRESENCE OF ALUMINA

Authors
HIRANO M YAKABE S CLARK JH KUDO H MORIMOTO T
Citation
M. Hirano et al., MANGANESE(III)-CATALYZED OXIDATION OF SULFIDES WITH SODIUM-CHLORITE IN AN APROTIC-SOLVENT IN THE PRESENCE OF ALUMINA, Synthetic communications, 26(10), 1996, pp. 1875-1886
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
10
Year of publication
1996
Pages
1875 - 1886
Database
ISI
SICI code
0039-7911(1996)26:10<1875:MOOSWS>2.0.ZU;2-K
Abstract
A wide variety of sulphides can be readily converted to the correspond ing sulphoxides in good to excellent yields by treatment with a combin ation of sodium chlorite, (salen)manganese(III) complex, and chromatog raphic alumina in dichloromethane under mild and neutral conditions.