Polar substance energy desorption study. This study suggests an extens
ion of the Dubinin-Radushkevich and Gibbs-Helmholtz equations, by usin
g adsorption forces in microporous composites. These forces, mainly th
ose of Van der Waals, have been set up in three groups of components a
ccording to their effects : unspecified forces, dispersion-perturbatio
n forces, quadrupole and dipole interaction forces. The suggested mode
ls take into account the different forces and present a good coherence
with the experiment.