A PRACTICAL SYNTHESIS OF (R)-(-CYCLOHEX-3-ENECARBOXYLIC ACID VIA AN ASYMMETRIC DIELS-ALDER REACTION())

Authors
THOM C KOCIENSKI P JAROWICKI K
Citation
C. Thom et al., A PRACTICAL SYNTHESIS OF (R)-(-CYCLOHEX-3-ENECARBOXYLIC ACID VIA AN ASYMMETRIC DIELS-ALDER REACTION()), Synthesis, (5), 1993, pp. 475-477
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
5
Year of publication
1993
Pages
475 - 477
Database
ISI
SICI code
0039-7881(1993):5<475:APSO(A>2.0.ZU;2-J
Abstract
The polymerisation which complicates the ethylaluminum dichloride-cata lysed asymmetric Diels-Alder reaction between N-propenoylbornane-10,2- sultam dimethyl-3-thia-4-azatricyclo-[5.2.1.0(1,5)]decane 3,3-dioxide] and butadiene can be suppressed using galvinoxyl yl-4-oxo-2,5-cyclohe xadien-1-ylidene)-p-tolyloxyl] leading to a practical and large scale synthesis of (R)-(+)-cyclohex-3-enecarboxylic acid.