T. Muranaka et Y. Hiwatari, STUDY ON THE BETA-PEAK OF CHI'' FOR A 2-DIMENSIONAL SUPERCOOLED FLUIDSTATE VIA MOLECULAR-DYNAMICS SIMULATION, Molecular simulation, 16(4-6), 1996, pp. 387-397
We have computed the generalized susceptibility (imaginary part of chi
) of two-dimensional supercooled fluid states through molecular dynami
cs simulations with different system sizes. It is found that when the
temperature of the system is higher than T-c (critical temperature) th
ere is no significant difference between the large (10,000-particle) a
nd small (100-particle) systems in the chi'' obtained, but for much lo
wer temperatures the spectra of the chi'' obtained reveal a remarkable
system-size dependent behavior such as the beta peak becomes much bro
ader for the large system. This phenomenon is physically understood in
terms of the strongly correlated motion of atoms extending over a wid
e range of space of the system. We will discuss in this work about the
relaxations on two-dimensional supercooled fluids and their microscop
ic origins as well as their system-size dependence.