The P2 centre was the first defect observed in diamond with electron s
pin resonance. Because of a very complicated ESR spectrum many years e
lapsed before the correct model was determined. Accurate spin Hamilton
ian parameters have been determined from extensive ENDOR measurements
at room temperature. These parameters are consistent with a model in w
hich the defect consists of three nitrogens plus a vacancy. The observ
ed ENDOR transitions do not follow the normal selection rules, and it
will be explained how it can be predicted what frequencies will presen
t in the ENDOR spectra.