Njb. Green et Sm. Pimblott, STOCHASTIC-ANALYSIS OF THE ASYMPTOTIC KINETICS OF MULTIPARTICLE SPURS, Journal of the Chemical Society. Faraday transactions, 89(9), 1993, pp. 1299-1304
Citations number
34
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Analyses are presented of the long-time asymptotic kinetics of spur re
actions in the absence of scavenger, and of the asymptotic concentrati
on dependence of the scavenging yield. The results show no dependence
on the initial spatial distribution of the particles apart from that i
nherent in the escape yield. However, the asymptotics are shown to pro
vide further information about the probability distribution of the num
bers of particles escaping, and hence to provide an indirect probe of
the initial number distribution.