A NEW DECAVANADATE DIHYDRATE TEMPLATED BY ETHYLENEDIAMINE

Citation
C. Ninclaus et al., A NEW DECAVANADATE DIHYDRATE TEMPLATED BY ETHYLENEDIAMINE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 512-514
Citations number
10
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
3
Pages
512 - 514
Database
ISI
SICI code
0108-2701(1996)52:<512:ANDDTB>2.0.ZU;2-U
Abstract
(C2H10N2)(3)[V10O28].2H(2)O, tris(ethylenediammonium) decavanadate dih ydrate, crystallizes in the monoclinic system (P2(1)/n), Its structure , solved by single-crystal X-ray diffraction with a final R value of 0 .0237 for 5136 unique reflections, is characterized by a pseudo body-c entred arrangement of the [V10O28](6-) polyanions, between which are i ntercalated the ethylenediammonium cations and the water molecules.