HENYLPHOSPHINE-P)]-(1-PHENYLPHOSPHIRANE-P)IRON(II) HEXAFLUOROPHOSPHATE

Authors
PABEL M WILLIS AC WILD SB
Citation
M. Pabel et al., HENYLPHOSPHINE-P)]-(1-PHENYLPHOSPHIRANE-P)IRON(II) HEXAFLUOROPHOSPHATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 557-559
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
3
Pages
557 - 559
Database
ISI
SICI code
0108-2701(1996)52:<557:HH>2.0.ZU;2-R
Abstract
The title compound, [Fe(C5H5)(C8H9P)(C20H20P2)]PF6, was obtained by sp ontaneous resolution of the racemate from acetone/diethyl ether soluti on. The cationic piano-stool iron(II) complex exhibits pseudo-octahedr al coordination geometry, with Fe-P distances of 2.189(3) and 2.178 (4 ) Angstrom for the bidentate ligand, and 2.170 (3) Angstrom for the ph osphirane ligand, The bond parameters for the phosphirane ligand are i n good agreement with those found for related complexes.