THE POLYMERIC CADMIUM COMPLEX Y-[MU-(NICOTINATO-O,O'N)-MU-BROMO-MONOAQUACADMIUM]

Authors
ZHANG CG XU DJ XU YZ HUANG XY
Citation
Cg. Zhang et al., THE POLYMERIC CADMIUM COMPLEX Y-[MU-(NICOTINATO-O,O'N)-MU-BROMO-MONOAQUACADMIUM], Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 591-593
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
3
Pages
591 - 593
Database
ISI
SICI code
0108-2701(1996)52:<591:TPCCY>2.0.ZU;2-T
Abstract
In the title complex, dmium-mu-bromo-mu-(3-pyridinecarboxylato-O,O':N) ], [CdBr(C6H4NO2)-(H2O)](n), the Cd-II atom is six-coordinate. The car boxyI; late group of the nicotinate anion coordinates to the Cd-II ato m as a chelate, with almost identical Cd-O distances [2.348 (3) and 2. 331(3) Angstrom] and a small chelating angle of 56.0(1)degrees. Both t he nicotinate and Br- anions bridge the Cd-II atoms to form polymeric di-catena chains in the crystal.