TETRAKIS(TRIETHYLAMMONIUM) HEXAKIS(ISOTHIOCYANATO-N)NICKEL(II)

Authors
KRUGER PE MCKEE V
Citation
Pe. Kruger et V. Mckee, TETRAKIS(TRIETHYLAMMONIUM) HEXAKIS(ISOTHIOCYANATO-N)NICKEL(II), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 617-619
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
3
Pages
617 - 619
Database
ISI
SICI code
0108-2701(1996)52:<617:TH>2.0.ZU;2-Q
Abstract
The unit cell of the title compound, (C6H16N)(4)[Ni-(NCS)(6)], contain s two independent centrosymmetric [Ni(NCS)(6)](4-) anions and eight Et (3)NH(+) cations. The Ni-N distances are in the range 2.072(4)-2.097 ( 4) Angstrom. In one anion, all six S atoms are hydrogen bonded to cati ons, but the second anion is involved in only two hydrogen bonds. Ther e are no significant geometrical differences between the two anions.