A BIS(6-METHYL-2-PYRIDYLMETHYL) THIOETHER (DMPT) COPPER(II) COMPLEX, [CU(OSO2CF3)(2)(C14H16N2S)].CH2CL2

Authors
DIEBOLD A KYRITSAKAS N FISCHER J WEISS R
Citation
A. Diebold et al., A BIS(6-METHYL-2-PYRIDYLMETHYL) THIOETHER (DMPT) COPPER(II) COMPLEX, [CU(OSO2CF3)(2)(C14H16N2S)].CH2CL2, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 632-634
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
3
Pages
632 - 634
Database
ISI
SICI code
0108-2701(1996)52:<632:ABT(CC>2.0.ZU;2-P
Abstract
The X-ray crystal structure determination of the title copper derivati ve, [bis(6-methyl-2-pyridylmethyl) sulfide-N,N', S] bis(trifluoromethy lsulfonato-O)copper (II) dichloromethane solvate, shows that this comp ound contains monomeric [Cu(DMPT)OSO2CF3)(2)] molecules in which the C u-II ion in surrounded by a tridentate DMPT ligand [Cu-N1 2.001(4), Cu -N2 1.977(4) and Cu-S3 2.319 (1) Angstrom] and by a pair of trifluorom ethylsulfonato ligands [Cu-O1 2.205(4) and Cu-O4 2.043 (3) Angstrom] i n a distorted tetragonal-pyramidal environment.