ENYLTHIOUREA-S)BIS(TRIPHENYLPHOSPHINE-P)COPPER(I), [CU(PPH(3))(2)(DBPTH)BR]

The coordination around the Cu-metal centre in the title compound, [CU Br(C15H24N2S)(C18H15P)(2)], is distorted tetrahedral with bond lengths Cu-S 2.367(1), Cu-Br 2.469(1), Cu-P(1) 2.279(2) and Cu-P(2) 2.284(2) Angstrom, and bond angles S-Cu-Br 111.86(5), S-Cu-P(1) 111.28(6), S-Cu -P(2) 98.01(6), Br-Cu-P(1) 103.08(5), Br-Cu-P(2) 108.60(5) and P(1)-Cu -P(2) 124.11(6)degrees. The H atom of the NH group is intramolecularly hydrogen bonded to the Br atom, with an NH ... Br distance of 2.411 A ngstrom.