U. Berens et G. Raabe, XY-5,6-BIS(HYDROXYMETHYL)-2,3-DIMETHYL-1,4-DIOXANE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 669-672
The title compound, C12H24O6, was synthesized and subjected to an X-ra
y structure determination. The aim of this structure analysis was to d
etermine the relative orientation of two vicinal ethoxy groups in its
precursor, diethyl 3R,5R,6R)-5,6-diethoxy-5,6-dimethyl-1,4-dioxane-2,
3-dicarboxylate, from which the title compound can be generated by a r
eaction that retains the absolute configuration of the molecular skele
ton.